By G. A. Burney, R. M. Harbour, National Research Council (U.S.). Subco
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Extra resources for Radiochemistry of neptunium
5M TTA given in xylene in Table Shepard tion for the extraction for a range of nitric cations into a,cid concentrations are 1 18. TA from many other elements. Basically, of Np to the fering the lTA method depends highly ions are (Procedures extractable stabilized tetravalent and co~letely hydro~lamine state in inextractable 1 and 2, p 138 and 141], IKl is rapidly on quantitative with hydrochloride-potassium hydrochloride-ferrous chloride. and Pu(III] remain in the aqueous fering cations directly alpha and U(W) for are present, emitters Fe(III), Zr(IVl, but separation ‘lTA-xylene do not if 1s verified into interfere.
L J :s o al Uclo. a. n I 14 4cI0. n m Ulo, 9, . M JI I a Ulo. e, . s, . >? :s 1 m Um3. - n, . n M n, . ho Ii n, . u s, . m, . U k, . m 0, . s, . 1s . u 1, . 0 0, . c, . J Np(IV), strong which exists complexes fores negatively trated most anions. charged chloro H(3 and HN03; these dangers. e of peroxide A purple-gray of Hz[hto Np(IV) a solution listed in TabI@ 15, the according to in- formedi by addition of the to Np*+: C104- NC indicates co-precipitation less percant under proper conditions. -42- w than a few includin~ the carriers me rare earths and Th also added to decrease line earths. The fluoride acid-soluble sulfates oIrto hydroxides precipitate with bromate but other and lanthanides removal again Np is reduced coprecipitated dioxide preceding precipitation with the alkallj. yields hydroxide. uoride-solubl(e Np(VI), and, hence, LaFs pre[:ipitation stelp. After to the state Ix)travalent Pa is co~trecipitated LaFS.
Radiochemistry of neptunium by G. A. Burney, R. M. Harbour, National Research Council (U.S.). Subco
NC indicates co-precipitation less percant under proper conditions. -42- w than a few includin~ the carriers me rare earths and Th also added to decrease line earths. The fluoride acid-soluble sulfates oIrto hydroxides precipitate with bromate but other and lanthanides removal again Np is reduced coprecipitated dioxide preceding precipitation with the alkallj. yields hydroxide. uoride-solubl(e Np(VI), and, hence, LaFs pre[:ipitation stelp. After to the state Ix)travalent Pa is co~trecipitated LaFS.